Simple, stereospecific syntheses of some insect pheromones using the iron tricarbonyl protecting group was written by Knox, Graham R.;Thom, Ian G.. And the article was included in Journal of the Chemical Society, Chemical Communications in 1981.Related Products of 50767-78-7 The following contents are mentioned in the article:
(Diene)Fe(CO)3 complexes have been used as starting materials for the stereospecific preparation of moth pheromones having (E)- and (E,E)-1,3-diene skeletons. E.g., acetylation of (CH2:CH)2Fe(CO)3 with ClCO(CH2)6CO2Et (AlCl3) followed sequentially by reduction (LiAlH4, AlCl3), acetylation (Ac2O, NaOAc), and cleavage of the Fe(CO)3 group (Me3NO) gave (E)-H2C:CHCH:CH(CH2)8OAc (I) with a stereochem. purity >99%. I is the pheromone of the red bollworm moth. This study involved multiple reactions and reactants, such as (E)-Dodeca-9,11-dien-1-yl acetate (cas: 50767-78-7Related Products of 50767-78-7).
(E)-Dodeca-9,11-dien-1-yl acetate (cas: 50767-78-7) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Related Products of 50767-78-7
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics