Narita, Tadashi et al. published their research in Makromolekulare Chemie in 1987 | CAS: 3063-94-3

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate

Anionic polymerization of fluorine-containing vinyl monomers. 6. Polymerizations of fluoroalkyl acrylates and methacrylates initiated by organoaluminum compounds was written by Narita, Tadashi;Hagiwara, Tokio;Hamana, Hiroshi;Miyasaka, Takehiko;Wakayama, Akira;Hotta, Tetsuo. And the article was included in Makromolekulare Chemie in 1987.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:

The anionic polymerizations of 2,2,2-trifluoroethyl acrylate (I), 2,2,2-trifluoroethyl methacrylate (II), 2,2,2-trifluoro-1-trifluoromethylethyl acrylate, and 2,2,2-trifluoro-1-trifluoromethylethyl methacrylate (III) were examined with Et3Al and diethylaluminum active methylene chelate compounds as initiators. III was polymerized with Et3Al. Diethyl(Et cyanoacetato)aluminum produced polymers of I and II. Diethyl(acetylacetonato)aluminum and diethyl(di-Me malonato)aluminum, however, showed low reactivity towards these 4 monomers. The resulting polymers showed unimodal mol. weight distribution with number-average mol. weights of 104-105, measured by gel chromatog. The initiation reaction and the copolymerization reactivity with styrene supported the anionic polymerization mechanism. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).

1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Liquid esters of low volatility serve as softening agents for resins and plastics. Esters also include many industrially important polymers. Polymethyl methacrylate is a glass substitute sold under the names Lucite and Plexiglas; polyethylene terephthalate is used as a film (Mylar) and as textile fibres sold as Terylene, Fortrel, and Dacron.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics