Lu, Zhichao published the artcileBase-Promoted Radical Azofluoromethylation of Unactivated Alkenes, Safety of 3-Methylbut-2-en-1-yl benzoate, the publication is Organic Letters (2020), 22(11), 4383-4388, database is CAplus and MEDLINE.
The base-induced reaction of aryl diazonium salts with com. available CF3SO2Na/CF2HSO2Na allows for the generation of the corresponding diazene radicals along with fluoromethyl radicals. The addition of fluoromethyl radicals to alkenes with subsequent diazene trapping provides the azofluoromethylation products in good to excellent yields. This metal-free method under mild reaction conditions has broad functional group compatibility and is applicable in the late-stage modification of various natural products and bioactive mols.
Organic Letters published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Safety of 3-Methylbut-2-en-1-yl benzoate.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics