Well-defined Cp*Co(III)-catalyzed Hydrogenation of Carbonates and Polycarbonates was written by Dahiya, Pardeep;Gangwar, Manoj Kumar;Sundararaju, Basker. And the article was included in ChemCatChem in 2021.Computed Properties of C13H10O3 The following contents are mentioned in the article:
The authors herein report the catalytic hydrogenation of carbonates and polycarbonates into their corresponding diols/alcs. using well-defined, air-stable, high-valent cobalt complexes. Several novel Cp*Co(III) complexes bearing N,O-chelation were isolated for the first time and structurally characterized by various spectroscopic techniques including single crystal X-ray crystallog. These novel Co(III) complexes have shown excellent catalytic activity to produce value added diols/alcs. from carbonate and polycarbonates through hydrogenation using mol. hydrogen as sole reductant or i-PrOH as transfer hydrogenation source. To demonstrate the developed methodol.’s practical applicability, the authors have recycled the bisphenol A monomer from compact disk (CD) through hydrogenation under the established reaction conditions using phosphine-free, earth-abundant, air- and moisture-stable high-valent cobalt catalysts. This study involved multiple reactions and reactants, such as Diphenyl carbonate (cas: 102-09-0Computed Properties of C13H10O3).
Diphenyl carbonate (cas: 102-09-0) belongs to esters. Esters are widespread in nature and are widely used in industry. In nature, fats are in general triesters derived from glycerol and fatty acids. Esters are responsible for the aroma of many fruits. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Computed Properties of C13H10O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics