Cooksey, John published the artcileThe nucleophilic addition of α-metallated 1,3-dioxanes to planar chiral cationic η3-allylmolybdenum complexes. Synthesis of (2E,5S,6R,7E)-6-methyl-8-phenylocta-2,7-dienoic acid methyl ester, a key component of the Cryptophycins, Application In Synthesis of 5205-11-8, the publication is Organic & Biomolecular Chemistry (2004), 2(12), 1719-1731, database is CAplus and MEDLINE.
Two adjacent stereogenic centers and a pendant alkene were constructed via nucleophilic addition of a 1,3-dioxan-4-ylcopper(I) reagent to a cationic η3-allylmolybdenum complex as part of a synthesis of (2E,5S,6R,7E)-5-hydroxy-6-methyl-8-phenylocta-2,7-dienoic acid Me ester (I), a key component of the Cryptophycins. Oxidative addition of Mo(CO)4(THF)2 to allyl benzoates provides an efficient synthesis of η3-allylmolybdenum(dicarbonyl) complexes.
Organic & Biomolecular Chemistry published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Application In Synthesis of 5205-11-8.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics