Du, Yiming published the artcileTransition-Metal-Free, Intermolecular Azidoheteroarylation of Alkenes: Efficient Access to β-Azidoalkylated Quinoxalinones and Preliminary Antifungal Evaluation Against Magnaporthe grisea, Product Details of C12H14O2, the publication is Synthesis (2020), 52(16), 2395-2409, database is CAplus.
An efficient, PhI(OAc)2-mediated, radical azidoheteroarylation of alkenes under transition-metal-free conditions is reported by employing TMSN3 and quinoxalin-2(1 H)-ones as coupling partners. This domino reaction allows an efficient synthesis of valuable orangoazides containing quinoxalin-2(1 H)-one derivatives and could be extended to phosphinyl-alkylated quinoxalin-2(1 H)-one in a single step in moderate to excellent yields under mild conditions, as demonstrated by the preliminary antifungal evaluation against Magnaporthe grisea for the first time. Mechanistic studies revealed that this transformation undergoes a cascade addition pathway controlled by a polar radical. Thus, e.g., 1-methylquinoxalin-2(1H)-one + 1-hexene + TMSN3 â?I (96%) in MeCN in presence of Li2CO3 as base and PhI(OAc)2 as oxidant.
Synthesis published new progress about 5205-11-8. 5205-11-8 belongs to esters-buliding-blocks, auxiliary class Alkenyl,Benzene,Ester, name is 3-Methylbut-2-en-1-yl benzoate, and the molecular formula is C12H14O2, Product Details of C12H14O2.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics