Barton, Lisa M. published the artcileElectrochemical borylation of carboxylic acids, COA of Formula: C14H28BNO4, the publication is Proceedings of the National Academy of Sciences of the United States of America (2021), 118(34), e2109408118, database is CAplus and MEDLINE.
A simple electrochem. mediated method for the conversion of alkyl carboxylic acids to their borylated congeners is presented. This protocol features an undivided cell setup with inexpensive carbon-based electrodes and exhibits a broad substrate scope and scalability in both flow and batch reactors. The use of this method in challenging contexts is exemplified with a modular formal synthesis of jawsamycin, a natural product harboring five cyclopropane rings.
Proceedings of the National Academy of Sciences of the United States of America published new progress about 1850305-80-4. 1850305-80-4 belongs to esters-buliding-blocks, auxiliary class Boronic acid and ester,Boronic Acids,Boronate Esters, name is tert-Butyl N-[3-(tetramethyl-1,3,2-dioxaborolan-2-yl)propyl]carbamate, and the molecular formula is C14H28BNO4, COA of Formula: C14H28BNO4.
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