Ananth, Ramagopal published the artcileOptical purification of chiral glycidyl arenesulfonates, Application In Synthesis of 115314-17-5, the publication is Tetrahedron: Asymmetry (1995), 6(2), 317-20, database is CAplus.
The m.p. point phase diagrams of glycidyl tosylate (1), glycidyl 3-nitrobenzenesulfonate (2), and trans-3-methylglycidyl tosylate (3) have been investigated. Compounds 1 and 2 exhibit a more significant solid solution behavior in the terminal zones of the phase diagram than 3, and are therefore more difficult to enrich enantiomerically by recrystallizations The crystallization of 2 in ethanol is further complicated by polymorphism which can be followed by differential scanning calorimetry. The effects of these properties on the optical purification of 1–3 are discussed.
Tetrahedron: Asymmetry published new progress about 115314-17-5. 115314-17-5 belongs to esters-buliding-blocks, auxiliary class Epoxides,Chiral,Nitro Compound,Sulfonate,Benzene, name is (R)-Oxiran-2-ylmethyl 3-nitrobenzenesulfonate, and the molecular formula is C9H9NO6S, Application In Synthesis of 115314-17-5.
Referemce:
https://en.wikipedia.org/wiki/Ester,
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