Gas-phase kinetics of OH radicals reaction with a series of fluorinated acrylates and methacrylates at atmospheric pressure and 298 K was written by Tovar, Carmen M.;Teruel, Mariano A.. And the article was included in Atmospheric Environment in 2014.HPLC of Formula: 3063-94-3 The following contents are mentioned in the article:
Rate coefficients for the gas phase reactions of OH radicals with 2,2,2-trifluoroethylmethacrylate (k1) 1,1,1,3,3,3-hexafluoroisopropylacrylate (k2), 1,1,1,3,3,3-hexafluoroisopropylmethacrylate (k3), and 2,2,2-trifluoroethylacrylate (k4) were determinated to be k1 = (2.54 ± 0.12) × 10-11, k2 = (1.41 ± 0.11) × 10-11, k3 = (1.65 ± 0.14) × 10-11 and k4 = (1.25 ± 0.13) × 10-11 cm3 mol.-1 s-1, resp. Kinetic experiments were performed at room temperature and atm. pressure using the relative-rate technique with GC-FID anal. This study is the first kinetic for these reactions of OH radicals under atm. pressure. Addnl., the rate constants obtained are compared with other halogenated and non halogenated acrylates and methacrylates to develop structure/reactivity relationships in terms of the presence of fluorine and ester groups and the hydrocarbon chain length. The atm. implications of the reactions were assessed by the estimation of the tropospheric lifetimes of the title reactions. This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3HPLC of Formula: 3063-94-3).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Esters perform as high-grade solvents for a broad array of plastics, plasticizers, resins, and lacquers, and are one of the largest classes of synthetic lubricants on the commercial market. Acyl chlorides and acid anhydrides alcoholysis is another way to produce esters. Acyl chlorides and acid anhydrides react with alcohols to produce esters. Anydrous conditions are recommended since both acyl chlorides and acid anhydrides react with water.HPLC of Formula: 3063-94-3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics