New synthetic reactions utilizing organosilicon and tin compounds was written by Ochiai, Masahito. And the article was included in Yakugaku Kenkyu no Shinpo in 1986.Computed Properties of C14H24O2 The following contents are mentioned in the article:
Synthesis of functionalized olefins utilizing organosilicon and tin compounds are described. The silicon-directed thermal elimination from β-triethylsilyl sulfoxides followed by protodesilylation provides a new method to achieve the regiospecific introduction of a double bond. Thus, thermolysis of PhCH2CH(CH2SiMe3)S(O)Ph, followed by protodesilylation, gave PhCH2CH:CH2. The desulfonation of vinyl sulfones via the β-elimination of β-tributylstannylorganosulfur compounds has been developed and the reaction was applied to the stereoselective synthesis of functionalized olefins, including 1,3-dienes, allenes, vinyl sulfides, vinylsilanes, vinylstannanes, and allylsilanes. Oxidative 1,4-fragmentation of γ-tributylstannyl alcs. using iodosylbenzene produces unsaturated carbonyl compounds; the fragmentation, combined with conjugate addition of tributylstannyllithium and reduction or alkylation, offers an efficient procedure for the reductive and alkylative ring opening of cyclic vinyl ketones. Medium size unsaturated lactones are synthesized by employing the fragmentation as a key step. This study involved multiple reactions and reactants, such as (E)-Dodeca-9,11-dien-1-yl acetate (cas: 50767-78-7Computed Properties of C14H24O2).
(E)-Dodeca-9,11-dien-1-yl acetate (cas: 50767-78-7) belongs to esters. Esters are also usually derived from carboxylic acids. It may also be obtained by reaction of acid anhydride or acid halides with alcohols or by the reaction of salts of carboxylic acids with alkyl halides. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Computed Properties of C14H24O2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics