Anselmi, E. published the artcilePerfluoroalkylation of aliphatic thiols in the presence of sodium hydroxymethanesulfinate, Category: esters-buliding-blocks, the publication is Journal of Fluorine Chemistry (2000), 105(1), 41-44, database is CAplus.
Direct perfluoroalkylation of aliphatic thiols was performed in the presence of sodium hydroxymethanesulfinate (Rongalite). Reaction of mercaptoalkanoic esters with trifluoromethyl bromide gave the corresponding trifluoromethylthio ethers. Condensation of alkane dithiols with perfluoroalkyl iodides led mainly to fluorinated dithioethers. These alkylation reactions are interpreted as occurring via in situ formation of dialkyl disulfides. A mixture of Rongalite and water was introduced to a mixture of Me mercaptoacetate and sodium phosphate in DMF. The flask was evacuated and bromotrifluoromethane (gas) was introduced while the pressure was maintained at 4.5 bar. After work-up the yield of Me [(trifluoromethyl)thio]acetate was 48%.
Journal of Fluorine Chemistry published new progress about 19788-49-9. 19788-49-9 belongs to esters-buliding-blocks, auxiliary class Thiol,Aliphatic hydrocarbon chain,Ester, name is Ethyl 2-mercaptopropanoate, and the molecular formula is C5H10O2S, Category: esters-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Ester,
Ester – an overview | ScienceDirect Topics