Proteins and muchin adsorption onto fluorinated poly(methacrylates) was written by Kojima, Masayoshi;Yokoyama, Yuichi;Kadoma, Yoshinori;Masuhara, Eiichi. And the article was included in Iyo Kizai Kenkyusho Hokoku (Tokyo Ika Shika Daigaku) in 1983.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate The following contents are mentioned in the article:
Trifluoroethyl聽methacrylate (I) [38785-10-3] was prepared from trifluoroethanol聽聽[75-89-8] and methacryloyl chloride (II) in 14% yield. Hexafluoroisopropyl聽methacrylate聽聽[3063-94-3](III) was prepared from hexafluoroisopropanol聽聽[920-66-1] and II in the presence of Et3N in 15% yield. Homopolymerization of I and its copolymerization with Me methacrylate (IV) were performed in the presence of 0.5% 2,2′-azobis-2,4-dimethyl-4-methoxyvaleronitrile at 0掳 in sealed tubes. The homopolymerization of III were carried out in the presence of Bz2O2 at 60掳 in C6H6. Polymers thus obtained were purified by reprecipitation from C6H6, CH2Cl2, or Me2CO/MeOH. Every polymer obtained was soluble in C6H6 etc., except III-homopolymer [28825-23-2] which was soluble in Et2O. Calf serum albumin (VI), egg white lysozyme (VII) [9001-63-2], and pig gastric mucin (VIII) were labeled with 125I, dissolved in pH 7.30 phosphate buffer solution, and were adsorbed on the polymer films prepared above. VI adsorption decreased slightly and that of VIII increased significantly with increasing I and III content in the copolymers with IV, whereas VII adsorption was not affected by the film composition This study involved multiple reactions and reactants, such as 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate).
1,1,1,3,3,3-Hexafluoroisopropylmethacrylate (cas: 3063-94-3) belongs to esters. Carboxylic acid esters of low molecular weight are colourless, volatile liquids with pleasant odours, slightly soluble in water. Esters are more polar than ethers but less polar than alcohols. They participate in hydrogen bonds as hydrogen-bond acceptors, but cannot act as hydrogen-bond donors, unlike their parent alcohols. This ability to participate in hydrogen bonding confers some water-solubility.Name: 1,1,1,3,3,3-Hexafluoroisopropylmethacrylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics