Zhu, Xiaoyi; Li, Ruibo; Yao, Hequan; Lin, Aijun published their research in Organic Letters in 2021. The article was titled 《Palladium-Catalyzed Allenamide Carbopalladation/Allylation with Active Methine Compounds》.Recommanded Product: Ethyl 2-methyl-3-oxobutanoate The article contains the following contents:
A palladium-catalyzed allenamide carbopalladation/allylation with active methine compounds has been developed. Various indoles and isoquinolinones bearing a quaternary carbon center were achieved with good efficiency, a broad substrate scope and good functional group tolerance. This reaction underwent cascade oxidative addition, carbopalladation, and allylic alkylation, and two new C-C bonds were formed in one pot. In the part of experimental materials, we found many familiar compounds, such as Ethyl 2-methyl-3-oxobutanoate(cas: 609-14-3Recommanded Product: Ethyl 2-methyl-3-oxobutanoate)
Ethyl 2-methyl-3-oxobutanoate(cas: 609-14-3) belongs to ketone compounds. Ketones are highly reactive, although less so than aldehydes, to which they are closely related. Much of their chemical activity results from the nature of the carbonyl group. Ketones readily undergo a wide variety of chemical reactions.Recommanded Product: Ethyl 2-methyl-3-oxobutanoate
Referemce:
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