Li, Guoshuai; Yan, Yifei; Zhang, Pengfei; Xu, Xiaohua; Jin, Zhong published their research in ACS Catalysis in 2021. The article was titled 《Palladium-Catalyzed meta-Selective C-H Functionalization by Noncovalent H-Bonding Interaction》.Quality Control of Methyl 4-fluorobenzoate The article contains the following contents:
Herein, a palladium-catalyzed meta-selective C-H olefination of aromatic carbonyl compounds such as acetophenone, benzaldehyde, Me benzoate, N,N-diisopropylbenzamide, etc. by noncovalent hydrogen-bonding interaction was reported. N,N’-Substituted ureas RNHC(O)NHR1 [R = cyclohexyl, 3,5-bis(trifluoromethyl)phenyl; R1 = cyclohexyl, 2-(2-cyanophenoxy)ethyl, 2-phenoxyethyl, etc.] were engineered to serve as a H-bonding donor for binding to the substrates and, meanwhile, achieve site-selective control by the integrated directing group. In addition to this study using Methyl 4-fluorobenzoate, there are many other studies that have used Methyl 4-fluorobenzoate(cas: 403-33-8Quality Control of Methyl 4-fluorobenzoate) was used in this study.
Methyl 4-fluorobenzoate(cas: 403-33-8) is an organic fluorinated building block used for the synthesis of various pharmaceutical compounds. It can be used for the preparation of Blonanserin.Quality Control of Methyl 4-fluorobenzoate
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