Wang, Jingjing; Jiang, Feng; Tao, Chaofu; Yu, Han; Ruhlmann, Laurent; Wei, Yongge published their research in Green Chemistry in 2021. The article was titled 《Oxidative esterification of alcohols by a single-side organically decorated Anderson-type chrome-based catalyst》.Synthetic Route of C8H7FO2 The article contains the following contents:
The direct esterification of alcs. with non-noble metal-based catalytic systems faces great challenges. Here, we report a new chrome-based catalyst stabilized by a single pentaerythritol decorated Anderson-type polyoxometalate, [N(C4H9)4]3[CrMo6O18(OH)3C{(OCH2)3CH2OH}], which can realize the efficient transformation from alcs. to esters by H2O2 oxidation in good yields and high selectivity without extra organic ligands. A variety of alcs. with different functionalities including some natural products and pharmaceutical intermediates are tolerated in this system. The chrome-based catalyst can be recycled several times and still keep the original configuration and catalytic activity. We also propose a reasonable catalytic mechanism and prove the potential for industrial applications. The results came from multiple reactions, including the reaction of Methyl 4-fluorobenzoate(cas: 403-33-8Synthetic Route of C8H7FO2)
Methyl 4-fluorobenzoate(cas: 403-33-8) is an organic fluorinated building block used for the synthesis of various pharmaceutical compounds. It can be used for the preparation of Blonanserin.Synthetic Route of C8H7FO2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics