Umeda, Takehiro; Minakata, Satoshi published their research in RSC Advances in 2021. The article was titled 《A practical method for the aziridination of α,β-unsaturated carbonyl compounds with a simple carbamate utilizing sodium hypochlorite pentahydrate》.Product Details of 4248-19-5 The article contains the following contents:
The efficient formation of tert-Bu N-chloro-N-sodio-carbamate by the reaction of simple tert-Bu carbamate with sodium hypochlorite pentahydrate (NaOCl.5H2O) would be a practical and green method for the aziridination of α,β-unsaturated carbonyl compds RCH=CH2 [R = methoxycarbonyl, (3,5-dimethyl-1H-pyrazol-1-yl)carbonyl, (anthracen-9-ylmethoxy)carbonyl, etc.]. The process described herein is transition-metal free, all of the materials are com. available, the byproducts (NaCl and H2O) are environmentally benign and the reaction is stereoselective. The resulting aziridines I are potential precursors of amino acids. The experimental part of the paper was very detailed, including the reaction process of tert-Butyl carbamate(cas: 4248-19-5Product Details of 4248-19-5)
tert-Butyl carbamate(cas: 4248-19-5) belongs to anime. Amines can be classified according to the nature and number of substituents on nitrogen. Aliphatic amines contain only H and alkyl substituents. Aromatic amines have the nitrogen atom connected to an aromatic ring.Important amines include amino acids, biogenic amines, trimethylamine, and aniline. Inorganic derivatives of ammonia are also called amines, such as monochloramine (NClH2).Product Details of 4248-19-5
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Ester – an overview | ScienceDirect Topics