In 2003,Ocal, Nuket; Yano, Lovelle M.; Erden, Ihsan published 《Photooxygenation of the C:N bond. A mild new method for oxidative C-C cleavage》.Tetrahedron Letters published the findings.Electric Literature of C4H8O3 The information in the text is summarized as follows:
Upon photooxygenation in the presence of base, α-oximino carbonyl compounds undergo clean oxidative C-C cleavage giving rise to mixtures of esters and acids. The mechanism of these reactions involves some unusual peroxidic intermediates, including a 2,3,5-trioxapentanes.Methyl 3-hydroxypropanoate(cas: 6149-41-3Electric Literature of C4H8O3) was used in this study.
Methyl 3-hydroxypropanoate(cas: 6149-41-3) belongs to esters with low molecular weight are commonly used as fragrances and found in essential oils and pheromones. Their flexibility and low polarity is manifested in their physical properties; they tend to be less rigid (lower melting point) and more volatile (lower boiling point) than the corresponding amides. Electric Literature of C4H8O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics