《Copper-Catalyzed sp3-Carbon Radical/Halogen Radical Cross Coupling: Selective Halogenation of 1,3-Dicarbonyl Compounds》 was written by Lv, Shuai-Shuai; Yan, Xu-Ping; Li, Cheng-Kun; Zhou, Shao-Fang; Shoberu, Adedamola; Zou, Jian-Ping. Computed Properties of C7H12O3 And the article was included in ChemistrySelect in 2020. The article conveys some information:
A new copper-catalyzed sp3-carbon radical/halogen radical cross-coupling strategy for the formation of C(sp3)-X bond is described. This provides a general method for synthesis of α-halogenated-1,3-dicarbonyl compounds RC(O)CH(Br)C(O)R1 (R = Ph, Me, 1-naphthyl, etc.; R1 = Ph, Me, ethoxy, etc.) and α,α-dihalogenated-1,3-dicarbonyl compounds RC(O)C(X)2C(O)R1 (X = Br, Cl) using sodium halides as halogen source under mild conditions. In addition to this study using Ethyl 3-oxopentanoate, there are many other studies that have used Ethyl 3-oxopentanoate(cas: 4949-44-4Computed Properties of C7H12O3) was used in this study.
Ethyl 3-oxopentanoate(cas: 4949-44-4) belongs to ketone compounds. They are most widely used as solvents, especially in industries manufacturing explosives, lacquers, paints, and textiles. Ketones are also used in tanning, as preservatives, and in hydraulic fluids.Computed Properties of C7H12O3
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics