《Long-Term Cyclability of NCM-811 at High Voltages in Lithium-Ion Batteries: an In-Depth Diagnostic Study》 was written by Li, Wangda; Liu, Xiaoming; Xie, Qiang; You, Ya; Chi, Miaofang; Manthiram, Arumugam. Application of 872-36-6 And the article was included in Chemistry of Materials in 2020. The article conveys some information:
High-nickel layered oxides, such as LiNi0.8Co0.1Mn0.1O2 (NCM-811), offer higher energy d. than their low-nickel counterparts at a given voltage and are gaining major traction in automotive lithium-ion batteries for elec. vehicles. Besides high-Ni content, higher charging voltages above 4.3 V vs Li+/Li boost the energy and represent another focus in battery development. Here, we investigate the long-term cyclability of NCM-811 in graphite pouch cells over 1000 deep cycles between 2.5-4.2, 2.5-4.4, and 2.5-4.5 V through a suite of sensitive characterization techniques. The NCM-811 full cells show severely deteriorated cyclability with higher charging voltages, from 78% at 4.2 V to 52 and 32% at 4.4 and 4.5 V, resp. At 4.2 V, minor parasitic electrolyte oxidation as well as cathode Li/Ni mixing and cracking are revealed after cycling, while transition-metal dissolution and surface reconstruction into rock-salt NiO are virtually undetectable. At 4.4 and 4.5 V, transition-metal dissolution and crossover to the anode become much more pronounced and a primary contributor to the capacity fade, while significant surface NiO formation causes substantial voltage polarization, which is less noticeable at 4.2 V. Meanwhile, more severe electrolyte oxidation, Li/Ni mixing, and particle pulverization exacerbate the voltage and capacity fade. These results outline distinct challenges for stable high-Ni layered oxide cathodes in high-voltage Li-ion batteries. The experimental process involved the reaction of Vinylene carbonate(cas: 872-36-6Application of 872-36-6)
Vinylene carbonate(cas: 872-36-6) belongs to esters. Alkyl carbonates find applications as solvents for lithium ion battery electrolytes and the use of high quality battery grade electrolytes having extremely low water (<10 ppm) and acid (<10 ppm) contents are critical for achieving high electrochemical performance.Application of 872-36-6
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Ester – an overview | ScienceDirect Topics