The author of 《Rhodium catalyzed template-assisted distal para-C-H olefination》 were Dutta, Uttam; Maiti, Sudip; Pimparkar, Sandeep; Maiti, Siddhartha; Gahan, Lawrence R.; Krenske, Elizabeth H.; Lupton, David W.; Maiti, Debabrata. And the article was published in Chemical Science in 2019. Name: Benzyl acrylate The author mentioned the following in the article:
Rhodium catalysis were extensively used for ortho-C-H functionalization reactions, and successfully extended to meta-C-H functionalization. Its application to para-C-H activation remained an unmet challenge. Herein The first example of such a reaction, with the Rh-catalyzed para-C-H olefination of arenes was disclosed to obtained para-olefinated arenes e.g., I. The use of a Si-linked cyanobiphenyl unit as a traceless directing group leads to highly para-selective arene-olefin couplings. In the experiment, the researchers used Benzyl acrylate(cas: 2495-35-4Name: Benzyl acrylate)
Benzyl acrylate(cas: 2495-35-4) is a reagent that can be used in the preparation of 2-(Phosphonomethyl)pentanedioic Acid, a selective glutamate carboxypeptidase 2 (GCP-II) inhibitor. It can also be used in the preparation of high refractive index polyacrylates.Name: Benzyl acrylate
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