In 2022,Bruckner, Eric P.; Curk, Tine; Djordjevic, Luka; Wang, Ziwei; Yang, Yang; Qiu, Ruomeng; Dannenhoffer, Adam J.; Sai, Hiroaki; Kupferberg, Jacob; Palmer, Liam C.; Luijten, Erik; Stupp, Samuel I. published an article in ACS Nano. The title of the article was 《Hybrid Nanocrystals of Small Molecules and Chemically Disordered Polymers》.Synthetic Route of C10H22N2O2 The author mentioned the following in the article:
Organic crystals formed by small mols. can be highly functional but are often brittle or insoluble structures with limited possibilities for use or processing from a liquid phase. A possible solution is the nanoscale integration of polymers into organic crystals without sacrificing long-range order and therefore function. This enables the organic crystals to benefit from the advantageous mech. and chem. properties of the polymeric component. We report here on a strategy in which small mols. cocrystallize with side chains of chem. disordered polymers to create hybrid nanostructures containing a highly ordered lattice. Synchrotron X-ray scattering, absorption spectroscopy, and coarse-grained mol. dynamics simulations reveal that the polymer backbones form an “”exo-crystalline”” layer of disordered chains that wrap around the nanostructures, becoming a handle for interesting properties. The morphol. of this “”hybrid bonding polymer”” nanostructure is dictated by the competition between the polymers’ entropy and the enthalpy of the lattice allowing for control over the aspect ratio of the nanocrystal by changing the degree of polymer integration. We observed that nanostructures with an exo-crystalline layer of polymer exhibit enhanced fracture strength, self-healing capacity, and dispersion in water, which benefits their use as light-harvesting assemblies in photocatalysis. Guided by computation, future work could further explore these hybrid nanostructures as components for functional materials. The experimental process involved the reaction of tert-Butyl (5-aminopentyl)carbamate(cas: 51644-96-3Synthetic Route of C10H22N2O2)
Some of the reported applications of tert-Butyl (5-aminopentyl)carbamate(cas: 51644-96-3) include: synthesis of of a supermacrocycle that self-assemble to form organic nanotubes., preparation of water-soluble unsymmetrical sulforhodamine fluorophores from monobrominated sulfoxanthene dye, synthesis of functionalized porphyrins as biocompatible carrier system for photodynamic therapy (PDT).Synthetic Route of C10H22N2O2
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics