On July 19, 2019, Verdelet, Tristan; Benmahdjoub, Sara; Benmerad, Belkacem; Alami, Mouad; Messaoudi, Samir published an article.Formula: C12H16O7 The title of the article was Copper-Catalyzed Anomeric O-Arylation of Carbohydrate Derivatives at Room Temperature. And the article contained the following:
Direct and practical anomeric O-arylation of sugar lactols with substituted arylboronic acids has been established. Using copper catalysis at room temperature under an air atm., the protocol proved to be general, and a variety of aryl O-glycosides have been prepared in good to excellent yields. Furthermore, this approach was extended successfully to unprotected carbohydrates, including α-mannose, and it was demonstrated here how the interaction between carbohydrates and boronic acids can be combined with copper catalysis to achieve selective anomeric O-arylation. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Formula: C12H16O7
The Article related to aryl glycoside preparation anomeric arylation sugar lactol arylboronic acid, Carbohydrates: Oligosaccharides and other aspects.Formula: C12H16O7
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