On December 18, 2020, Tomita, Shunpei; Tanaka, Masamichi; Inoue, Michitaka; Inaba, Kazuki; Takahashi, Daisuke; Toshima, Kazunobu published an article.Related Products of 2873-29-2 The title of the article was Diboron-Catalyzed Regio- and 1,2-cis-α-Stereoselective Glycosylation of trans-1,2-Diols. And the article contained the following:
Regio- and 1,2-cis-α-stereoselective glycosylations were investigated using 1,2-anhydroglucose donors and trans-1,2-diol sugar acceptors in the presence of a diboron catalyst. The reactions proceeded smoothly to provide the corresponding 1,2-cis-α-glycosides with consistently very high stereoselectivity and were regioselectivity controlled by the protecting groups of the acceptor. The present glycosylation method was applied successfully to the efficient synthesis of α-1,3-glucan pentasaccharide. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Related Products of 2873-29-2
The Article related to oligosaccharide preparation regioselective stereoselective glycosylation boron catalyzed glycoside pentasaccharide, Carbohydrates: Oligosaccharides and other aspects.Related Products of 2873-29-2
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