On March 5, 2021, Takeda, Daiki; Yoritate, Makoto; Yasutomi, Hiroki; Chiba, Suzuka; Moriyama, Takahiro; Yokoo, Atsushi; Usui, Kazuteru; Hirai, Go published an article.Synthetic Route of 2873-29-2 The title of the article was β-Glycosyl Trifluoroborates as Precursors for Direct α-C-Glycosylation: Synthesis of 2-Deoxy-α-C-glycosides. And the article contained the following:
C-Glycosides are metabolically stable mimics of natural O-glycosides and are expected to be useful tools for investigation of the biol. functions of glycans. Here, we describe the synthesis of a series of aryl and vinyl C-glycosides by stereoinvertive sp3-sp2 cross-coupling reactions of 2-deoxyglycosyl boronic acid derivatives with aryl or vinyl halide, mediated by a photoredox/nickel dual catalytic system. Hydrogenation of the vinyl C-glycosides afforded C-linked 2′-deoxydisaccharide analogs. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Synthetic Route of 2873-29-2
The Article related to c deoxyglycoside preparation glycosyl trifluoroborate glycosylation aryl halide, Carbohydrates: Oligosaccharides and other aspects.Synthetic Route of 2873-29-2
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