On February 1, 2019, Sakamoto, Kana; Nagai, Masaki; Ebe, Yusuke; Yorimitsu, Hideki; Nishimura, Takahiro published an article.Related Products of 2873-29-2 The title of the article was Iridium-Catalyzed Direct Hydroarylation of Glycals via C-H Activation: Ligand-Controlled Stereoselective Synthesis of α- and β-C-Glycosyl Arenes. And the article contained the following:
Diastereoselective direct hydroarylation of glycals with aromatic compounds was realized by use of an iridium/binap catalyst, giving the corresponding C-glycosyl compounds in high yields. The use of binap with the different absolute configuration enabled the stereoselective synthesis of α- or β-C-glycosyl arenes irresp. of the chirality of the glycals. The method showing the high functional group tolerance provides an atom-economical access to C-glycosyl arenes by way of C-H bond activation. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Related Products of 2873-29-2
The Article related to c aryl glycoside stereoselective hydroarylation iridium catalyzed glycosyl arene, Carbohydrates: Glycosides and other aspects.Related Products of 2873-29-2
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