Esteves, Henrique A.; Darbem, Mariana P.; Pimenta, Daniel C.; Stefani, Helio A. published an article in 2019, the title of the article was Carbonylative Negishi-Type Coupling of 2-Iodoglycals with Alkyl and Aryl Halides.SDS of cas: 2873-29-2 And the article contains the following content:
C-Glycosides are valuable organic compounds in the field of medicinal chem. due to their ubiquity inside living systems and pronounced biol. activity. Herein, we describe an approach to alkyl-ketones bearing glycal units, e.g. I, via the Pd-catalyzed carbonylative coupling of 2-iodoglycals and alkyl and aryl halides. Examples bearing a variety of functional groups are presented as well as a mechanistic proposal for this transformation. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).SDS of cas: 2873-29-2
The Article related to carbonylative, glycoside preparation negishi coupling iodoglycal halide alkylketone glycosylation catalyst, Carbohydrates: Glycosides and other aspects.SDS of cas: 2873-29-2
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