On July 31, 2019, Dong, Youxian; Ding, Zekun; Guo, Hong; Zhou, Le; Jiang, Nan; Chen, Heshan; Qiu, Saifeng; Xu, Xiaoxia; Zhang, Jianbo published an article.Computed Properties of 2873-29-2 The title of the article was A Highly Efficient Magnetic Iron(III) Nanocatalyst for Ferrier Rearrangements. And the article contained the following:
A novel and highly efficient magnetic Fe 3O 4@C@Fe(III) core-shell catalyst, in which the carbon shell was prepared from lotus leaf, was fabricated. This nanocatalyst was successfully applied in the synthesis of a series of 2,3-unsaturated O-glycosides in excellent yields and with high selectivity, especially in the case of 2-halo O-glycosides, which differ in reactivity from nonsubstituted O-glycosides, but which have scarcely been explored before. Moreover, the catalyst could be easily separated from the reaction by the application of an external magnetic force and reused a min. of five times without any significant decrease in the yields of the products. In addition, the reaction proceeded readily on a gram scale, which provides a bright prospect for future applications. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Computed Properties of 2873-29-2
The Article related to magnetic iron carbon shell nanocatalyst green synthesis ferrier rearrangement, unsaturated glycoside preparation ferrier rearrangement glycal alc magnetic nanocatalyst, Carbohydrates: Oligosaccharides and other aspects.Computed Properties of 2873-29-2
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