On September 6, 2013, Zhang, Ningning; Yang, Rui; Zhang-Negrerie, Daisy; Du, Yunfei; Zhao, Kang published an article.Reference of tert-Butyl 2-(4-nitrophenyl)acetate The title of the article was Direct Conversion of N-Alkoxyamides to Carboxylic Esters through Tandem NBS-Mediated Oxidative Homocoupling and Thermal Denitrogenation. And the article contained the following:
Treatment of N-alkoxyamides with NBS in toluene was found to conveniently afford the corresponding carboxylic esters, including those bearing a bulky or long-chain substituent, in satisfactory to excellent yields. This approach not only represents a convenient and economical approach to a direct transformation of an alkoxyamide moiety into the carboxylic ester functional group, via oxidative homocoupling and the subsequent thermal denitrogenation, but also facilitates the synthesis of sterically hindered carboxylic esters. The experimental process involved the reaction of tert-Butyl 2-(4-nitrophenyl)acetate(cas: 29704-38-9).Reference of tert-Butyl 2-(4-nitrophenyl)acetate
The Article related to alkoxy amide preparation conversion carboxylic ester nbs, General Organic Chemistry: Synthetic Methods and other aspects.Reference of tert-Butyl 2-(4-nitrophenyl)acetate
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