On August 7, 2018, Xie, Sheng-Ming; Fu, Nan; Li, Li; Yuan, Bao-Yan; Zhang, Jun-Hui; Li, Yan-Xia; Yuan, Li-Ming published an article.Quality Control of (R)-Methyl 3-hydroxybutanoate The title of the article was Homochiral Metal-Organic Cage for Gas Chromatographic Separations. And the article contained the following:
Metal-organic cages (MOCs) as a new type of porous material with well-defined cavities were extensively pursued because of their relative ease of synthesis and their potential applications in host-guest chem., mol. recognition, separation, catalysis, gas storage, and drug delivery. Here, the authors 1st reported that a homochiral MOC [Zn3L2] is explored to fabricate [Zn3L2] coated capillary column for high-resolution gas chromatog. separation of a wide range of analytes, including n-alkanes, polycyclic aromatic hydrocarbons, and positional isomers, especially for racemates. Various kinds of racemates such as alcs., diols, epoxides, ethers, halohydrocarbons, and esters were separated with good enantioselectivity and reproducibility on the [Zn3L2] coated capillary column. The fabricated [Zn3L2] coated capillary column exhibited significant chiral recognition complementary to that of a com. β-DEX 120 column and the authors’ recently reported homochiral porous organic cage CC3-R coated column. The homochiral MOCs will be very attractive as a new type of chiral selector in separation science. The experimental process involved the reaction of (R)-Methyl 3-hydroxybutanoate(cas: 3976-69-0).Quality Control of (R)-Methyl 3-hydroxybutanoate
The Article related to homochiral metal organic cage gc stationary phase chiral recognition, Organic Analytical Chemistry: Separations and other aspects.Quality Control of (R)-Methyl 3-hydroxybutanoate
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