Kusumoto, Sotaro; Koga, Atsushi; Kobayashi, Fumiya; Ohtani, Ryo; Kim, Yang; Lindoy, Leonard F.; Hayami, Shinya; Nakamura, Masaaki published an article in 2019, the title of the article was Weak ferromagnetism derived from spin canting in an amido-bridged homochiral Mn(III) 1-D coordination polymer.Application of 118-55-8 And the article contains the following content:
A homochiral one-dimensional (1D) Mn(III) coordination polymer [MnL]n (1) was synthesized employing the N3O-donor tetradentate ligand (L = 2-hydroxy-N-[2-[[(2-aminophenyl)methylene]amino]-2-methylpropyl]-benzamide). The X-ray structure of 1 and its magnetic properties were investigated in detail. The crystal structure of 1 shows a homochiral helical arrangement in which spontaneous resolution has occurred, despite the ligand being achiral. Magnetic characterization revealed an antiferromagnetic interaction between manganese(III) ions (J = -2.48 cm-1, g = 1.96) that leads to an antiferromagnetic spin-ordering phase transition at TN ≈ 7 K. Noteworthily, 1 exhibits weak ferromagnetism with a relatively large coercive field of 3.0 kOe based on the spin canting, indicating the formation of a homochiral weak ferromagnet. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Application of 118-55-8
The Article related to polymer amido bridge manganese complex spin canting ferromagnetism, Placeholder for records without volume info and other aspects.Application of 118-55-8
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