On August 26, 2022, Karmakar, Ujjwal; Hwang, Ho Seong; Lee, Yunjeong; Cho, Eun Jin published an article.Formula: C9H11NO2 The title of the article was Photocatalytic para-Selective C-H Functionalization of Anilines with Diazomalonates. And the article contained the following:
Visible-light-induced para-selective C-H functionalization of anilines over N-H insertion was developed using diazomalonates with the help of an Ir(III) photocatalyst. The para-selective radical-radical cross coupling proceeded via C-centered radical intermediates generated from both anilines and diazomalonates. The photochem. of anilines could be extended to other N-heterocycles, such as indole and carbazole. The reaction pathway for the selective C-C coupling was validated by electrochem. and photophys. experiments as well as computational studies. The experimental process involved the reaction of Methyl N-Methylanthranilate(cas: 85-91-6).Formula: C9H11NO2
The Article related to photocatalytic para selective alkylation aniline diazomalonate, General Organic Chemistry: Synthetic Methods and other aspects.Formula: C9H11NO2
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