On September 14, 2020, Uyanik, Muhammet; Sahara, Naoto; Tsukahara, Mayuko; Hattori, Yuhei; Ishihara, Kazuaki published an article.Product Details of 10472-24-9 The title of the article was Chemo- and Enantioselective Oxidative α-Azidation of Carbonyl Compounds. And the article contained the following:
The authors report high-performance I+/H2O2 catalysis for the oxidative or decarboxylative oxidative α-azidation of carbonyl compounds by using sodium azide under biphasic neutral phase-transfer conditions. To induce higher reactivity especially for the α-azidation of 1,3-dicarbonyl compounds, the authors designed a structurally compact isoindoline-derived quaternary ammonium iodide catalyst bearing electron-withdrawing groups. The nonproductive decomposition pathways of I+/H2O2 catalysis could be suppressed using a catalytic amount of a radical-trapping agent. This oxidative coupling tolerates a variety of functional groups and could be readily applied to the late-stage α-azidation of structurally diverse complex mols. Moreover, the authors achieved the enantioselective α-azidation of 1,3-dicarbonyl compounds as the first successful example of enantioselective intermol. oxidative coupling with a chiral hypoiodite catalyst. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Product Details of 10472-24-9
The Article related to chemo enantioselective oxidative alpha azidation catalyst carbonyl, azides, chemoselectivity, enantioselectivity, hypoiodite catalysis, oxidative coupling, General Organic Chemistry: Synthetic Methods and other aspects.Product Details of 10472-24-9
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics