On May 26, 2021, Saito, Masato; Kawamata, Yu; Meanwell, Michael; Navratil, Rafael; Chiodi, Debora; Carlson, Ethan; Hu, Pengfei; Chen, Longrui; Udyavara, Sagar; Kingston, Cian; Tanwar, Mayank; Tyagi, Sameer; McKillican, Bruce P.; Gichinga, Moses G.; Schmidt, Michael A.; Eastgate, Martin D.; Lamberto, Massimiliano; He, Chi; Tang, Tianhua; Malapit, Christian A.; Sigman, Matthew S.; Minteer, Shelley D.; Neurock, Matthew; Baran, Phil S. published an article.Recommanded Product: Methyl 1-methyl-4-oxocyclohexanecarboxylate The title of the article was N-Ammonium Ylide Mediators for Electrochemical C-H Oxidation. And the article contained the following:
Herein, a rationally designed platform that provides a step toward this challenge using N-ammonium ylides e.g., acetamidotrimethylazanium-tetrafluoroboranuide as electrochem. driven oxidants for site-specific, chemoselective C(sp3)-H oxidn was presented. By taking a first-principles approach guided by computation, these new mediators were identified and rapidly expanded into a library using ubiquitous building blocks and trivial synthesis techniques. The ylide-based approach to C-H oxidation exhibits tunable selectivity that is often exclusive to this class of oxidants and can be applied to real-world problems in the agricultural and pharmaceutical sectors. The experimental process involved the reaction of Methyl 1-methyl-4-oxocyclohexanecarboxylate(cas: 37480-41-4).Recommanded Product: Methyl 1-methyl-4-oxocyclohexanecarboxylate
The Article related to ketone preparation regioselective chemoselective, aldehyde preparation regioselective chemoselective, hydrocarbon electrochem oxidation, ammonium ylide preparation, General Organic Chemistry: Synthetic Methods and other aspects.Recommanded Product: Methyl 1-methyl-4-oxocyclohexanecarboxylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics