Jin, Shengfei; Haug, Graham C.; Trevino, Ramon; Nguyen, Viet D.; Arman, Hadi D.; Larionov, Oleg V. published an article in 2021, the title of the article was Photoinduced C(sp3)-H sulfination empowers the direct and chemoselective introduction of the sulfonyl group.Synthetic Route of 10472-24-9 And the article contains the following content:
A photoinduced C-H sulfination of abundant C(sp3)-H bonds mediated by sodium metabisulfite to provide organosulfur compounds RSO2R1 [R = Me, allyl, F, etc.; R1 = cyclohexyl, n-pentyl, tetrahydrofuran-2-yl, etc.] was reported. Despite the importance of the sulfonyl group in synthesis, medicine and materials science, a direct C(sp3)-H sulfination reaction that could converted abundant aliphatic C-H bonds to sulfinates had remained elusive, due to the reactivity of sulfinates that were incompatible with typical oxidation-driven C-H functionalization approaches. The reaction proceeded with high chemoselectivity and moderate to good regioselectivity, afforded only monosulfination products and could be used for a solvent-controlled regiodivergent distal C(sp3)-H functionalization. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Synthetic Route of 10472-24-9
The Article related to organosulfur compound chemoselective preparation regioselective crystal structure mol, aliphatic compound photoinduced sulfination sodium metabisulfite mediated, Aliphatic Compounds: Sulfoxides and Sulfones and other aspects.Synthetic Route of 10472-24-9
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