On July 18, 2012, Roosen, Philipp C.; Kallepalli, Venkata A.; Chattopadhyay, Buddhadeb; Singleton, Daniel A.; Maleczka, Robert E.; Smith, Milton R. published an article.Category: esters-buliding-blocks The title of the article was Outer-Sphere Direction in Iridium C-H Borylation. And the article contained the following:
The NHBoc group affords ortho selective C-H borylations in arenes and alkenes. Exptl. and computational studies support an outer sphere mechanism where the N-H proton H bonds to a boryl ligand O. The regioselectivities are unique and complement those of directed ortho metalations. The experimental process involved the reaction of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate(cas: 141940-37-6).Category: esters-buliding-blocks
The Article related to iridium catalyzed borylation arene alkene regiochem, Organometallic and Organometalloidal Compounds: Boron Compounds and other aspects.Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics