On January 18, 2013, Ren, Hong; Wulff, William D. published an article.Application In Synthesis of (R)-Methyl 3-hydroxybutanoate The title of the article was Total Synthesis of Sedum Alkaloids via Catalyst Controlled aza-Cope Rearrangement and Hydroformylation with Formaldehyde. And the article contained the following:
The catalytic asym. aminoallylation of chiral aldehydes is developed as a new method for the catalyst controlled synthesis of syn- and anti-1,3-aminoalcs. This methodol. is highlighted in the synthesis of the sedum alkaloids (+)-sedridine (I) and (+)-allosedridine (II) both of which have their final carbon incorporated during closure of the piperidine ring via a hydroformylation with formaldehyde. The experimental process involved the reaction of (R)-Methyl 3-hydroxybutanoate(cas: 3976-69-0).Application In Synthesis of (R)-Methyl 3-hydroxybutanoate
The Article related to enantioselective synthesis sedum alkaloid azo cope rearrangement hydroformation, sedridine allosedridine enantioselective synthesis aminoallylation, Alkaloids: Alkaloids Containing One Nitrogen Atom In A Ring and other aspects.Application In Synthesis of (R)-Methyl 3-hydroxybutanoate
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