On June 30, 2017, Park, Heemin; Kwon, Yongseok; Shin, Jae Eui; Kim, Woo-Jung; Hwang, Soonho; Lee, Seokwoo; Kim, Sanghee published an article.Quality Control of (Trimethoxymethyl)benzene The title of the article was Orthoester in Cyclodehydration of Carbamate-Protected Amino Alcohols under Acidic Conditions. And the article contained the following:
The first acid-promoted reaction system to form azaheterocycles from N-carbamate-protected amino alcs. is described. The reaction involves the activation of the hydroxyl group via the use of orthoesters. Despite the reduced nucleophilicity of carbamate nitrogen, this reaction system provides several types of pyrrolidines and piperidines in good to high yields. Using this protocol, prolinol derivatives can also be synthesized from carbamate-protected amino diols with regio- and stereoselectivity. The experimental process involved the reaction of (Trimethoxymethyl)benzene(cas: 707-07-3).Quality Control of (Trimethoxymethyl)benzene
The Article related to carbamate protected amino alc orthoester cyclodehydration, pyrrolidine preparation, piperidine preparation, Heterocyclic Compounds (One Hetero Atom): Pyrroles and Pyrrolizines and other aspects.Quality Control of (Trimethoxymethyl)benzene
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics