On February 26, 2020, Guo, Yinliang; Guo, Zhixian; Lu, Jia-Tian; Fang, Runting; Chen, Si-Cong; Luo, Tuoping published an article.Application In Synthesis of Methyl 2-cyclopentanonecarboxylate The title of the article was Total Synthesis of (-)-Batrachotoxinin A: A Local-Desymmetrization Approach. And the article contained the following:
An enantioselective total synthesis of (-)-batrachotoxinin A is accomplished based on a key photoredox coupling reaction and the subsequent local-desymmetrization operation (I + II → III → IV). After the expedient assembly of the highly oxidized steroid skeleton, a delicate sequence of redox manipulations was carried out to deliver a late-stage intermediate on gram scale-and ultimately (-)-batrachotoxinin A (V) in an efficient manner. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Application In Synthesis of Methyl 2-cyclopentanonecarboxylate
The Article related to batrachotoxinin a enantioselective total synthesis photoredox coupling desymmetrization, Alkaloids: Alkaloids Containing One Nitrogen Atom In A Ring and other aspects.Application In Synthesis of Methyl 2-cyclopentanonecarboxylate
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