On October 26, 2016, Moon, Patrick J.; Yin, Shengkang; Lundgren, Rylan J. published an article.Recommanded Product: Ethyl 2-(4-(trifluoromethoxy)phenyl)acetate The title of the article was Ambient Decarboxylative Arylation of Malonate Half-Esters via Oxidative Catalysis. And the article contained the following:
We report decarboxylative carbonyl α-arylation by coupling of arylboron nucleophiles with malonic acid derivatives This process is enabled by the merger of aerobic oxidative Cu catalysis with decarboxylative enolate interception reminiscent of malonyl-CoA reactivity in polyketide biosynthesis. This method enables the synthesis of monoaryl acetate derivatives containing electrophilic functional groups that are incompatible with existing α-arylation reactivity paradigms. The utility of the reaction is demonstrated in drug intermediate synthesis and late-stage functionalization. The experimental process involved the reaction of Ethyl 2-(4-(trifluoromethoxy)phenyl)acetate(cas: 1206550-93-7).Recommanded Product: Ethyl 2-(4-(trifluoromethoxy)phenyl)acetate
The Article related to monoaryl acetate preparation, decarboxylative arylation coupling arylboron nucleophile malonic acid, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Esters, Acyl Peroxides, Acyl Halides and other aspects.Recommanded Product: Ethyl 2-(4-(trifluoromethoxy)phenyl)acetate
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Ester – an overview | ScienceDirect Topics