On September 1, 2021, Matsumoto, Akira; Shiozaki, Yoko; Sakurai, Shunya; Maruoka, Keiji published an article.Computed Properties of 10472-24-9 The title of the article was Synthesis of Functionalized Aliphatic Acid Esters via the Generation of Alkyl Radicals from Silylperoxyacetals. And the article contained the following:
We describe a catalytic method for the synthesis of a variety of functionalized aliphatic acid esters using silylperoxyacetals, which are versatile alkyl radical precursors with a terminal ester moiety. In the presence of an appropriate transition-metal catalyst, the in situ generation of alkyl radicals and the subsequent bond-forming process proceeds smoothly to afford synthetically valuable aliphatic acid derivatives [e.g., silylperoxyacetal I + PhCONH2 → II (83%) in presence of CuI/1,10-phenanthroline]. The present method can be applied to the efficient synthesis of a pharmaceutically important 1,1-diarylalkane motif. In addition, a novel strategy for the synthesis of structurally diverse hydroxy acid derivatives via a C-O bond formation process that utilizes TEMPO has been developed. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Computed Properties of 10472-24-9
The Article related to aliphatic acid ester synthesis silylperoxy acetal alkyl radical generation, c−c bond cleavage, alkyl radicals, hydroxy acids, iron-catalysis, silylperoxyacetals, β-scission and other aspects.Computed Properties of 10472-24-9
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics