Kusumoto, Sotaro; Kobayashi, Fumiya; Ohtani, Ryo; Zhang, Yingjie; Harrowfield, Jack; Kim, Yang; Hayami, Shinya; Nakamura, Masaaki published an article in 2018, the title of the article was Creating capsules with cubanes.Synthetic Route of 118-55-8 And the article contains the following content:
A sextuply linked capsule incorporating two Ni(II) cubane units is formed when Ni(II) salts are reacted with N-aminoalkyl salicylamidato ligands in a 4:3 ratio in methanol. With a short (propyl) alkyl substituent, addnl. chloride counterions are included in the cavity by occupation of one apex of each of the linked cubanes, while with a longer (pentyl) substituent, perchlorate and tetrafluoroborate anions are included, probably by H-bonding involving hydroxyl groups on the inner apexes of the cubanes, indicating that the cavity can be regarded as suited to binding of hydrophilic units despite the lipophilic character of its links. The dicubane capsules show ferromagnetic behavior typical of Ni(II) cubanes in general, with coupling constants dependent upon the nature of the salt-derived counteranions. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Synthetic Route of 118-55-8
The Article related to nickel aminoalkyl salicylamidato capsule cubane complex preparation crystal structure, thermal stability magnetic property nickel aminoalkyl salicylamidato capsule cubane and other aspects.Synthetic Route of 118-55-8
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