On August 7, 2020, Ai, Han-Jun; Zhang, Youcan; Zhao, Fengqian; Wu, Xiao-Feng published an article.Computed Properties of 118-55-8 The title of the article was Rhodium-Catalyzed Carbonylative Synthesis of Aryl Salicylates from Unactivated Phenols. And the article contained the following:
In the presence of RhCl3 and 1,2-bis(dicyclohexylphosphino)ethane (dcpe), phenols underwent carbonylative esterification reactions with CO mediated by TEMPO in 1.4-dioxane/toluene to yield aryl salicylates such as Ph salicylate. Under similar conditions, but using 1,3-bis(diphenylphosphino)propane as the ligand, di-Ph carbonate was obtained as the major product. The mechanism of the reaction was studied using the reactions of potential intermediates and using kinetic isotope effects. The experimental process involved the reaction of Phenyl Salicylate(cas: 118-55-8).Computed Properties of 118-55-8
The Article related to aryl hydroxybenzoate preparation, rhodium catalyst carbonylative esterification phenol, kinetic isotope effect mechanism rhodium catalyzed carbonylative esterification phenol and other aspects.Computed Properties of 118-55-8
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