On July 15, 2011, Zhu, Mingzhao; Zheng, Nan published an article.Category: esters-buliding-blocks The title of the article was Photoinduced cleavage of N-N bonds of aromatic hydrazines and hydrazides by visible light. And the article contained the following:
A photocatalytic system involving [Ru(bpyrz)3](PF6)2·2H2O, visible light, and air has been developed for cleavage of the N-N bonds of hydrazines and hydrazides. This catalytic system is generally effective for N,N-disubstituted hydrazine and hydrazide derivatives, including arylhydrazides, N-alkyl-N-arylhydrazines, and N,N-diarylhydrazines. The utility of this cleavage reaction has been demonstrated by synthesizing a variety of secondary aromatic amines. The experimental process involved the reaction of tert-Butyl (4-(trifluoromethyl)phenyl)carbamate(cas: 141940-37-6).Category: esters-buliding-blocks
The Article related to secondary aromatic amine synthesis electrophilic amination, aromatic hydrazine hydrazide photoinduced catalytic cleavage nitrogen light ruthenium, amines, cleavage, nitrogen–nitrogen bonds, ruthenium, visible light and other aspects.Category: esters-buliding-blocks
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics