On June 4, 1993, Wei, Yen; Bakthavatchalam, R.; Jin, Xian Ming; Murphy, Christopher K.; Davis, Franklin A. published an article.Synthetic Route of 121129-31-5 The title of the article was Effect of aggregation on stereochemistry and mechanism of asymmetric oxidation of the lithium enolate of methyl 3,3-dimethylbutanoate in the solid state and in solution. And the article contained the following:
Oxidation of the title enolate by enantiopure (camphorylsulfonyl)oxaziridines in THF afforded α-hydroxy ester with 53-73% ee, but the product from the solid state reactions was racemic. The results suggest that the enolate exists and reacts as an aggregate in the solid state reactions. The experimental process involved the reaction of Methyl 2-hydroxy-3,3-dimethylbutanoate(cas: 121129-31-5).Synthetic Route of 121129-31-5
The Article related to asym oxidation lithium enolate mechanism, enantiopure camphorylsulfonyloxaziridine oxidation lithium enolate, stereoselective oxidation lithium enolate, solid state oxidation lithium enolate and other aspects.Synthetic Route of 121129-31-5
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