On March 1, 2020, Shiozaki, Yoko; Sakurai, Shunya; Sakamoto, Ryu; Matsumoto, Akira; Maruoka, Keiji published an article.Synthetic Route of 2873-29-2 The title of the article was Iron-Catalyzed Radical Cleavage/C-C Bond Formation of Acetal-Derived Alkylsilyl Peroxides. And the article contained the following:
A novel radical-based approach for the Fe-catalyzed selective cleavage of acetal-derived alkylsilyl peroxides, followed by the formation of a C-C bond is reported. The reaction proceeds under mild reaction conditions and exhibits a broad substrate scope with respect to the acetal moiety and the C electrophile. Mechanistic studies suggest that the present reaction proceeds through a free-radical process involving C radicals generated by the homolytic cleavage of a C-C bond within the acetal moiety. A synthetic application of this method to sugar-derived alkylsilyl peroxides is also described. The experimental process involved the reaction of (2R,3S,4R)-2-(Acetoxymethyl)-3,4-dihydro-2H-pyran-3,4-diyl diacetate(cas: 2873-29-2).Synthetic Route of 2873-29-2
The Article related to iron catalyzed radical cleavage bond formation acetal alkylsilyl peroxide, c−c bond cleavage, c−c bond formation, alkylsilyl peroxides, iron-catalysis, radical reaction, sugar derivatives and other aspects.Synthetic Route of 2873-29-2
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