On February 12, 1993, Shi, Guo-qiang; Schlosser, Manfred published an article.COA of Formula: C10H11FO2 The title of the article was A novel and versatile access to fluorinated carbo- and heterocyclic compounds employing electron-rich fluorodienes as cycloaddition components. And the article contained the following:
The readily accessible 2-fluoro-1-trimethylsiloxy-1,3-dienes undergo Diels-Alder type cycloaddition with a variety of dienophiles under mild conditions. In this way, fluoro-2-cyclohexenols, fluoro-2,5-dihydropyranols, fluoro-2,5-dihydro-2-pyridinols, fluoropyridines, fluoro-3,6-dihydro-1,2-oxazines and fluoropyrroles can be efficiently prepared The experimental process involved the reaction of Ethyl 3-fluoro-4-methylbenzoate(cas: 86239-00-1).COA of Formula: C10H11FO2
The Article related to diels alder fluorotrimethylsiloxybutadiene, butadiene fluorotrimethylsiloxy diels alder, cyclohexenol fluoro, pyranol fluorodihydro, pyridinol fluorodihydro, pyridine fluoro, oxazine fluorodihydro, pyrrole fluoro and other aspects.COA of Formula: C10H11FO2
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