Seki, Tomohiro; McEleney, Kevin; Crudden, Cathleen M. published an article in 2012, the title of the article was Enantioselective catalysis with a chiral, phosphane-containing PMO material.Product Details of 3976-69-0 And the article contains the following content:
A novel bistriethoxysilyl-BINAP monomer was prepared and co-condensed with a biphenylene-bridged siloxane precursor in the presence of surfactant templates to give periodic mesoporous organosilicas (PMOs) functionalized with BINAP. Complexation of ruthenium followed by asym. catalytic hydrogenation and asym. transfer hydrogenation were carried out, and demonstrated that high levels of activity and selectivity are achievable with the chiral material. The experimental process involved the reaction of (R)-Methyl 3-hydroxybutanoate(cas: 3976-69-0).Product Details of 3976-69-0
The Article related to mesoporous organosilica binap ruthenium preparation enantioselective catalyst, bistriethoxysilyl binap preparation condensation siloxane precursor, ruthenium mesoporous organosilica binap complex preparation asym transfer hydrogenation and other aspects.Product Details of 3976-69-0
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