Okumura, Mikiko; Nakamata Huynh, Stephanie M.; Pospech, Jola; Sarlah, David published an article in 2016, the title of the article was Arenophile-Mediated Dearomative Reduction.Formula: C10H14O3 And the article contains the following content:
A dearomative reduction of simple arenes has been developed which employs a visible-light-mediated cycloaddition of arenes with an N-N-arenophile (N-methyl-1,2,4-triazoline-3,5-dione, MTAD) and in situ diimide reduction Subsequent cycloreversion or fragmentation of the arenophile moiety affords 1,3-cyclohexadienes, e.g., I, or 1,4-diaminocyclohex-2-enes, e.g., II, compounds that are not synthetically accessible using existing dearomatization reactions. Importantly, this strategy also provides numerous opportunities for further derivatization as well as site-selective functionalization of polynuclear arenes. The experimental process involved the reaction of (Trimethoxymethyl)benzene(cas: 707-07-3).Formula: C10H14O3
The Article related to arene methyltriazolinedione dearomative cycloaddition diimide reduction light cycloreversion fragmentation, cyclohexadiene preparation, cycloreverdiaminocyclohexene preparation, arenes, arenophiles, dearomatization, functionalization, photochemistry and other aspects.Formula: C10H14O3
Referemce:
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