On April 2, 2021, Liao, Zhehui; Zhang, Jiantao; Cao, Tongxiang; Zhu, Shifa published an article.Quality Control of Methyl 2-cyclopentanonecarboxylate The title of the article was Copper-Catalyzed Asymmetric Synthesis of Bicyclo[3.n.1]alkenones. And the article contained the following:
A series of highly strained bicyclo[3.n.1]alkenones such as I (R = Me, Et, i-Pr) have been successfully constructed in good to excellent enantioselectivities and moderate to good yields by copper-catalyzed formal [3+3] cycloaddition reaction of 2-oxocycloalkanecarboxylates and aryl vinyl ketones or arylethenyl vinyl ketones via nonracemic oxoalkyl-substituted oxocycloalkanecarboxylates such as II (R = Me, Et, i-Pr). The cycloadducts were selectively converted into various valuable bicyclic ring systems holding considerable potential for the construction of natural and bioactive compounds containing a [3.n.1] moiety. The experimental process involved the reaction of Methyl 2-cyclopentanonecarboxylate(cas: 10472-24-9).Quality Control of Methyl 2-cyclopentanonecarboxylate
The Article related to bicycloalkenone enantioselective preparation, copper catalyst enantioselective cycloaddition ketocycloalkanecarboxylate aryl vinyl ketone, enantioselective copper catalyzed michael addition oxocycloalkanecarboxylate vinyl ketone cyclocondensation and other aspects.Quality Control of Methyl 2-cyclopentanonecarboxylate
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