Kirby, Gordon W.; Nazeer, Muhammad published an article in 1988, the title of the article was Asymmetric induction in the Diels-Alder reactions of α-hydroxyacylnitroso compounds.Recommanded Product: Methyl 2-hydroxy-3,3-dimethylbutanoate And the article contains the following content:
Transient, chiral α-hydroxyacylnitroso compounds, RCH(OR1)CONO (R = Ph, R1 = OH, OMe; R = CMe3, cyclohexyl, R1 = OH), form intramol. hydrogen bonds, react stereoselectively with cyclopentadiene and cyclohexa-1,3-diene to yield the cycloadducts I and II. The cycloadduct of cyclohexadiene and the nitroso derivative of (S)-mandelic acid has been converted into the known (-)-oxazine derivative III. The experimental process involved the reaction of Methyl 2-hydroxy-3,3-dimethylbutanoate(cas: 121129-31-5).Recommanded Product: Methyl 2-hydroxy-3,3-dimethylbutanoate
The Article related to hydroxyacylnitroso compound desls alder stereoselectivity, cyclopentadiene diels alder hydroxyacylnitroso compound stereochem, cyclohexadiene diels alder hydroxyacylnitroso compound stereochem, asym induction diels alder hydroxyacylnitroso compound, oxazine derivative and other aspects.Recommanded Product: Methyl 2-hydroxy-3,3-dimethylbutanoate
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